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Facile syntheses of fluorine-containing α,β-unsaturated acids and esters from 2-trifluoromethylacrylic acid

✍ Scribed by Takamasa Fuchikami; Yoshiko Shibata; Yasuyuki Suzuki


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
249 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis


Various types of fluorine-containing a.B-unsaturated acids and their esters were synthesized from 2-trilfuoromethylacrylic acid as a sole starting material.


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Facile stereoselective syntheses of aryl
✍ Rui-Qi Pan; Ping-An Wang; Min-Zhi Deng 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 1 views

## Abstract The Suzuki‐type cross‐coupling reaction of arylboronic acids **3** with ethyl (Z)‐3‐iodo‐4,4,4‐trifluoro‐2‐butenoate **2**, which was generated by hydroiodination of available ethyl 4,4,4‐trifluoro‐2‐butynoate **1**, to afford ethyl (E)‐3‐aryl‐4,4,4‐trifluoro‐2‐butenoates **4**, was stu