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Facile Syntheses and Structures of New Metal−Maleonitrilediselenolates [K([2.2.2]-cryptand)] 3 [Ag(Se 2 C 2 (CN) 2 )(Se 6 )], [K([2.2.2]-cryptand)] 2 [Ni(Se 2 C 2 (CN) 2 ) 2 ], and Ni(dppp)(Se 2 C 2 (CN) 2 )

✍ Scribed by McLauchlan, Craig C.; Ibers, James A.

Book ID
127005416
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
47 KB
Volume
39
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES

[Ag{Se2C2(CN)2}(Se6)]3−, [Sb{Se2C2(CN)2}
[Ag{Se2C2(CN)2}(Se6)]3−, [Sb{Se2C2(CN)2}2]3− und [As(Se)3(CH2CN)]2−: einfache Bildung des Maleonitrildiselenolat(mns)-Liganden [Se2C2(CN)2]2−
✍ Donna M. Smith; Thomas E. Albrecht-Schmitt; James A. Ibers 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 88 KB 👁 1 views

Liganden enthalten, sowie über die Synthese von 3, die Hinweise auf den Mechanismus der Bildung von 1 und 2 liefern könnte. Wir erhielten 1 durch Umsetzen von [{IrCl(cod)} 2 ] mit AgBF 4 und [K([2.2.2]cryptand)] 2 [Se n ] (n 3, 5, 6) in flüssigem Ammoniak und anschlieûende Extraktion des Rückstands

Synthesis and Characterization of the Si
Synthesis and Characterization of the Silver Maleonitrilediselenolates and Silver Maleonitriledithiolates [K([2.2.2]-cryptand)] 4 [Ag 4 (Se 2 C 2 (CN) 2 ) 4 ], [Na([2.2.2]-cryptand)] 4 [Ag 4 (S 2 C 2 (CN) 2 ) 4 ]·0.33MeCN, [NBu 4 ] 4 [Ag 4 (S 2 C 2 (CN) 2 ) 4 ], [K([2.2.2]-cryptand)] 3 [Ag(Se 2 C 2 (CN) 2 ) 2 ]·2MeCN, and [Na([2.2.2]-cryptand)] 3 [Ag(S 2 C 2 (CN) 2 ) 2 ]
✍ McLauchlan, Craig C.; Ibers, James A. 📂 Article 📅 2001 🏛 American Chemical Society 🌐 English ⚖ 114 KB