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Facile Reductive Cyclizations. New Routes to Heterocycles. II 1

โœ Scribed by Taylor, Edward C.; McKillop, Alexander; Ross, Robert E.


Book ID
126465118
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
727 KB
Volume
87
Category
Article
ISSN
0002-7863

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The intramolecular sila-Pummerer cycliza
โœ Ian W. J. Still; F. Dean Toste ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 713 KB

The generality of the intramolecular cyclization of suitable nucleophilic sites to a -S+=CH2 center created by a sila-Pummerer rearrangement has been investigated. Successful nucleophilic sites included the OH group (in alcohols, carboxylic acids, and hydroxylamines) and the N H group (in amines and