Facile Reductive Cyclizations. New Routes to Heterocycles. 1 I
โ Scribed by Taylor, Edward C.; McKillop, Alexander
- Book ID
- 125942116
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 904 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The generality of the intramolecular cyclization of suitable nucleophilic sites to a -S+=CH2 center created by a sila-Pummerer rearrangement has been investigated. Successful nucleophilic sites included the OH group (in alcohols, carboxylic acids, and hydroxylamines) and the N H group (in amines and
Reaction of manganic acetate with organic disulphides in dichloromethanetrifluoroacetic acid in the presence of a variety of unsaturated amides leads to intramolecular cyclisation with formation of sulphenylated oxazolines, oxazines or tetrahydropyrroles. The addition of aryl sulphenyl halides and