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Facile Reduction of Azides with Sodium Borohydride/Copper (II) Sulphate System

✍ Scribed by Prakash rao, H. Surya; Siva, P.

Book ID
119956965
Publisher
Taylor and Francis Group
Year
1994
Tongue
English
Weight
234 KB
Volume
24
Category
Article
ISSN
0039-7911

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πŸ“œ SIMILAR VOLUMES

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## Abstract Copper(0) does not catalyze the decomposition of dialkylcarbamoyl azides **5a–e** but instead it is oxidized to copper(II) while the azides **5** are reduced by uptaking one electron per molecule and eliminating nitrogen. A probable explanation for the formation of the resulting copper(

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O-acyl derivatives of aldoximes and ketoximes are reduced in good yields to the corresponding amines with sodium borohydride-iodine system. Recent paper1 on the reduction of aromatic oximes with borohydride system prompts us to report our results on the transformation of oximes to amines. This rea