𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Facile preparation of the individual diastereomers of thymidine 3′,5′-cyclic phosphorothioate (cTMPS)

✍ Scribed by Alan E. Sopchik; Wesley G. Bentrude


Book ID
107858306
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
206 KB
Volume
22
Category
Article
ISSN
0040-4039

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## The stereochemical course of the epoxide-induced oxidative rearrangement of ribonucleoside cyclic 3',5'phosphorothioates into the corresponding 2',3'-phosphates has been determined using styrene ['80] oxide and (Sp)-uridine cyclic 3',5'-phosphorothioate. The evidence of full stereoselectivity of