Facile Preparation of Divalent Sialoside Derivatives by Olefin Metathesis Reaction
✍ Scribed by Zhonghong Gan; René Roy
- Book ID
- 104202511
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 128 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0040-4020
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✦ Synopsis
Olefin metathesis catalyzed by RuCl 2 (CHPh)(PCy 3 ) 2 (1) has been used to synthesize homodimers of O-and S-alkenyl a-sialoside derivatives. The reactions afforded reasonable to good yields under mild reaction conditions. Trans-geometrical isomers were preferred in all cases.
📜 SIMILAR VOLUMES
Hyaluronan and heparan sulfate disaccharides of the type b-D-glucuronic acid-(13)-N-acetyl-b-D-glucosamine and a-L-iduronic acid-( 14)-N-acetyl-b-D-glucosamine, respectively, with an n-pentenyl group at the reducing end have been synthesized. Homodimerization of these derivatives using Grubbs cataly
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v