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Facile Preparation of Divalent Sialoside Derivatives by Olefin Metathesis Reaction

✍ Scribed by Zhonghong Gan; René Roy


Book ID
104202511
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
128 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis


Olefin metathesis catalyzed by RuCl 2 (CHPh)(PCy 3 ) 2 (1) has been used to synthesize homodimers of O-and S-alkenyl a-sialoside derivatives. The reactions afforded reasonable to good yields under mild reaction conditions. Trans-geometrical isomers were preferred in all cases.


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