𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Facile optical resolution of DL-1,4,5,6-tetra-O-benzyl-myo-inositol: Key synthons for the phosphoinositides

✍ Scribed by R. Aneja; A. Parra


Book ID
104215595
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
166 KB
Volume
35
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


The facile preparation of lD-l,4,5,6-tetra-0-benzyl-myu-inositol and its enantiomer lL-1,4,5,6-tetra-0-benzyl-myo-inositol from the corresponding racemate via the l-(1 'S)-(-)-camphanic acid esters is described.


πŸ“œ SIMILAR VOLUMES


Synthesis of the enantiomeric 1,4,5,6-te
✍ Karol S. Bruzik; Grzegorz M. SalamoΕ„czyk πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 490 KB

The synthesis of the optically pure 1,4,5,6-tetra-O-benzyl-myo-inositols was achieved in four steps via diastereomeric 2,3-spire-acetals of myo-inositol with Land D-camphor as the key intermediates. Camphor dimethyl acetal was used for the acetalation reaction. The diastereomers were benzylated and