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Facile, Mild, and Highly Enantioselective Alkynylzinc Addition to Aromatic Aldehydes by BINOL/N-Methylimidazole Dual Catalysis.

โœ Scribed by Fei Yang; Peihua Xi; Li Yang; Jingbo Lan; Rugang Xie; Jingsong You

Publisher
John Wiley and Sons
Year
2007
Weight
28 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

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Highly Enantioselective Addition of Diphenylzinc to Aliphatic and Aromatic Aldehydes Catalyzed by a Readily Available H8-Binol Derivative
โœ Ying-Chuan Qin; Lin Pu ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 131 KB ๐Ÿ‘ 2 views

Chiral a-substituted benzyl alcohols are ubiquitous in the structure of organic compounds. A straightforward synthesis of these compounds involves the nucleophilic addition of a phenyl-metal reagent to an aldehyde which produces a carbon-carbon bond and a stereogenic center simultaneously. Because o