𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Highly Enantioselective Addition of Diphenylzinc to Aliphatic and Aromatic Aldehydes Catalyzed by a Readily Available H8-Binol Derivative

✍ Scribed by Ying-Chuan Qin; Lin Pu

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
131 KB
Volume
45
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Highly Enantioselective Addition of Diph
Highly Enantioselective Addition of Diphenylzinc to Aliphatic and Aromatic Aldehydes Catalyzed by a Readily Available H8-Binol Derivative
✍ Ying-Chuan Qin; Lin Pu πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 131 KB πŸ‘ 2 views

Chiral a-substituted benzyl alcohols are ubiquitous in the structure of organic compounds. A straightforward synthesis of these compounds involves the nucleophilic addition of a phenyl-metal reagent to an aldehyde which produces a carbon-carbon bond and a stereogenic center simultaneously. Because o

Room temperature and highly enantioselec
Room temperature and highly enantioselective additions of alkyltitanium reagents to aldehydes catalyzed by a titanium catalyst of (R)-h8-binol
✍ Qinghan Li; Han-Mou Gau πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 482 KB πŸ‘ 2 views

## Abstract  Three alkyltitanium reagents of RTi(O‐__i__‐Pr)~3~ (R = Cy (**1a**), __i__‐Bu (**1b**), and __n__‐Bu (**1c**)) were prepared in good yields. The high‐resolution mass spectroscopy showed that **1b** and 1**c** in the gas phase are monomeric species. However, the solid state of **1a** re