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Facile enantiodivergence of meso-1,3-diacyl-2-imidazolidinones to chiral 2-imidazolidinone auxiliaries

✍ Scribed by Kazuhiro Yokoyama; Tadao Ishizuka; Naoko Ohmachi; Takehisa Kunieda

Book ID: 104259443
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 197 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)00918-6

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✦ Synopsis

The enantioselective monodeacylation of meso-1,3-diacetyl-2-imidazolidinones, by treatmenmt with the lithium salts of sterically constrained N,N -dimethylaminoalcohol gives 1-acetyl-2-imidazolidinones in 89% ee. Thc lattcr compounds serve as good precursors lor efficient chiral auxiliaries.

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