Facile conversion of azides to amines
โ Scribed by Samarendra N. Maiti; Maya P. Singh; Ronald G. Micetich
- Book ID
- 104218358
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 116 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
[reaction: see text] A straightforward and highly efficient synthesis of aromatic azides from the corresponding amines is accomplished using triflyl azide under mild conditions.
Azides were converted to the corresponding carbamates using a system of 20 mol% of decaborane (B 10 H 14 ) and 20 weight% of 10% Pd/C in methanol in the presence of di-tert-butyl dicarbonate at rt in high yields and to the corresponding amines using a system of 10 mol% of decaborane and 20 weight% o
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