Facile and highly stereoselective allylation of aldehydes using allyltrichlorosilanes in DMF
✍ Scribed by Shū Kobayashi; Koichi Nishio
- Book ID
- 108380405
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 218 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Stereohomogeneous (E)-and (Z) -crotyltrifluorosilanes were prepared and used for the highly diastereoselective synthesis of threo-and erythro-/?-methylhomoallyl alcohols, respectively, from aldehydes in the presence of fluoride ions. The mechanism of the reaction was discussed. Recently, we have re
## Abstract Isomerically pure allylsilanes react with aldehydes in the presence of Lewis‐basic catalysts to produce the corresponding syn‐ and anti‐allylbromohydrins (III) and (V), respectively as single diastereomers.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v