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ChemInform Abstract: Synthesis of γ-Functionalized Allyltrichlorosilanes and Their Application in the Asymmetric Allylation of Aldehydes.

✍ Scribed by Andrei V. Malkov; Claire MacDonald; Pavel Kocovsky

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Isomerically pure allylsilanes react with aldehydes in the presence of Lewis‐basic catalysts to produce the corresponding syn‐ and anti‐allylbromohydrins (III) and (V), respectively as single diastereomers.

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