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Facile addition reactions of allylsilanes to quinolines and isoquinolines activated by chloroformate ester and a catalytic amount of triflate ion

โœ Scribed by Ryohei Yamaguchi; Tatsuya Nakayasu; Bunpei Hatano; Teruno Nagura; Sinpei Kozima; Ken-ichi Fujita


Book ID
108371041
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
157 KB
Volume
57
Category
Article
ISSN
0040-4020

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Triflate ion-promoted addition reactions
โœ Ryohei Yamaguchi; Bunpei Hatano; Tatsuya Nakayasu; Sinpei Kozima ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 209 KB

Reaction of allyltrimethylsilane with a variety of quinolines acylated by chloroformate esters can be promoted by a catalytic amount of a triflate ion to afford 2-allyl-l,2-dihydroquinolines in good to high yields. A similar reaction with isoquinolines afforded benzoisoquinuclidine derivatives by co