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Facile [3,3]-sigmatropic rearrangement in the reaction of α-chloroperfluorostyrene with allyl alcohol

✍ Scribed by V. G. Andreev; A. F. Kolomiets; K. V. Dvornikova; V. E. Platonov


Book ID
112424228
Publisher
Springer
Year
1992
Tongue
English
Weight
116 KB
Volume
41
Category
Article
ISSN
1573-9171

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[3,3] Sigmatropic rearrangement of allyl
✍ Stanley Raucher; Ki-Whan Chi; David S. Jones 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 231 KB

3,3] Sigmatropic rearrangement of allylic alcohols with ethyl P,P-diethoxyacrylate provides a convenient method for the regiospecific synthesis of substituted allylmalonates 2. The [3,3] sigmatropic rearrangement of ally1 vinyl ether derivatives to 7,b-unsaturated carbonyl compounds provides an extr