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Stereospecific [2,3] sigmatropic rearrangement of allylic sulfoxides and selenoxides. Synthesis of novel polycyclic allylic alcohols and α-hydroxy ketones

✍ Scribed by Marek Koprowski; Ewa Krawczyk; Aleksandra Skowroñska; Mary McPartlin; Nick Choi; Sanja Radojevic


Book ID
108371069
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
302 KB
Volume
57
Category
Article
ISSN
0040-4020

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First synthesis of optically pure selenu
✍ Noriyuki Kurose; Tamiko Takahashi; Toru Koizumi 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 740 KB

The first synthesis of optically pure selenuranes 1 has been accomplished by utilizing 2exo-hydroxy-10-bomyl group as a chiral ligand. Complete retention of the configuration has been observed in alkaline hytl'olysis of 1 to give selenoxides 2. The structure of 1 and2 has been fully established by X