F2 flourination of olefins containing H atoms
β Scribed by L. Conte; G.P. Gambaretto; E. Legnaro; C. Gervasutti; M. Pianca
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 48 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-1139
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Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.2