✦ LIBER ✦

F-to-HF reactions. IX. Nonthermal complications for the CH4/C3F6/C2F6 moderated nuclear recoil system

✍ Scribed by Chester A. Mathis; John W. Root

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 855 KB
Volume: 14
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550141102

No coin nor oath required. For personal study only.

✦ Synopsis

Results are reported from moderated nuclear recoil lSF experiments with the CH*/C~FG/ CzFs mixture system. At a 99.5% confidence level measurement precision of f3.4%, nonthermal F-to-HF reactions are phenomenologically suppressed a t CzFB moderator concentrations in the range of 95.0-99.95 mol-%. Effectively equilibrium reaction conditions can be established in well-designed experiments of this type.

📜 SIMILAR VOLUMES

F-to-HF reactions. VIII. Nonthermal comp

F-to-HF reactions. VIII. Nonthermal complications for the CHF3/C3F6/C2F6 moderated nuclear recoil system

✍ Chester A. Mathis; Rafael Gurvis; Mark Knickelbein; Kathleen D. Knierim; Siu-Hon 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 955 KB

Results are reported from moderated nuclear recoil I8F experiments with the 273 K CHF:+/C:,F~/CZF~ system. Although the measurement sensitivity is only about f12%, there is no evidence to support the occurrence of nonthermal F-to-HF reactions at 95 mol % CzFe moderator concentration.

Lightly fluorous [Pd(OAc)2{P(C6H4-p-SiMe

Lightly fluorous [Pd(OAc)2{P(C6H4-p-SiMe2CH2CH2C6F13)3}2] in the methoxycarbonylation of styrene: Formation, performance and stability of the catalyst system

✍ Jeroen J.M. de Pater; Berth-Jan Deelman; Cornelis J. Elsevier; Gerard van Koten 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 252 KB

Synthesis and characterization of aryl(t

Synthesis and characterization of aryl(trifluoromethyl)bismuth compounds (R-C6H4)3-nBi(CF3)n [R=H, 4-CH3, 4-CF3, 3-F, 4-F; n=1 and 2] and the reactions of (C6H5)3-nnBi(CF3)n [n=0–3] with benzoylpyridinium chloride

✍ N.V. Kirij; S.V. Pasenok; Yu.L. Yagupolskii; D. Naumann; W. Tyrra 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 510 KB

Isospecific Propylene Polymerization Usi

Isospecific Propylene Polymerization Using the [ArN(CH2)3NAr]TiCl2/Al(iBu)3/Ph3CB(C6F5)4 Catalyst System in the Presence of Cyclohexene

✍ Toshiya Uozumi; Shingo Tsubaki; Jizhu Jin; Tsuneji Sano; Kazuo Soga 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB 👁 1 views

Measurement of absolute rate data for th

Measurement of absolute rate data for the reaction of atomic potassium, K(42S½), with CH3F, C2H5F, C6H5F, CH3Br, C2H5Br, HCl and HBr by time-resolved atomic resonance absorption spectroscopy at λ = 404 nm (K(52PJ) ← K(42S½))

✍ D. Husain; Y. H. Lee 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 846 KB

We present a kinetic study of atomic potassium in its electronic ground state, K(4'SI 21, generated in the "single-shot mode" by pulsed irradiation at elevated temperatures and monitored by time-resolved atomic resonance absorption spectroscopy using the Rydberg doublet at A = 404 nm (K[5'PJ] +K[42S

Non-metallocene group 4 organometallic c

Non-metallocene group 4 organometallic complexes as catalysts for olefin polymerization: synthesis and catalytic activity of the cationic complex [Zr(CH2Ph)3]+ [B(CH2Ph) (C6F5)3]−

✍ Claudio Pellecchia; Alfonso Grassi; Adolfo Zambelli 📂 Article 📅 1993 🏛 Elsevier Science ⚖ 616 KB