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Extrusion Processing and Properties of Protein-Based Thermoplastics

✍ Scribed by Casparus J. R. Verbeek; Lisa E. van den Berg


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
357 KB
Volume
295
Category
Article
ISSN
1438-7492

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✦ Synopsis


Abstract

Increasing interest in competitive, sustainable, and biodegradable alternatives to petroleum‐based plastics has encouraged the developmentof protein‐based plastics. The formation of a homogeneous protein melt during extrusion occurs through: denaturation, dissociation, unraveling, and alignment of polymer chains. The presence of covalent cross‐links is unfavorable, decreasing chain mobility, increasing viscosity and preventing homogenization. Proteins have high softening temperatures, often above their decomposition temperatures. To avoid degradation, the required chain mobility is achieved by plasticizers. By understanding a protein's physiochemical nature, additives can be selected that lead to a bioplastic with good processability. The final structural and functional properties are highly dependent on the protein and processing conditions.

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