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Extremely facile formation and high reactivity of new thioacylsilanes containing the ferrocene moiety

โœ Scribed by Bianca F Bonini; Mauro Comes-Franchini; Mariafrancesca Fochi; Germana Mazzanti; Alfredo Ricci; Greta Varchi

Book ID
104262001
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
256 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Thioacylsilanes containing the ferrocene moiety, easily prepared from the corresponding acylsilanes with Lawesson's reagent at room temperature, can be transformed into vinyl silanes, sulfur heterocycles and sulfines.

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ChemInform Abstract: Extremely Facile Fo
ChemInform Abstract: Extremely Facile Formation and High Reactivity of New Thioacylsilanes Containing the Ferrocene Moiety.
โœ Bianca F. Bonini; Mauro Comes-Franchini; Mariafrancesca Fochi; Germana Mazzanti; ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

Extremely Facile Formation and High Reactivity of New Thioacylsilanes Containing the Ferrocene Moiety. -Thioacylsilanes (I) show high reactivity towards ether diazoacetate (II), dienes such as (VI), and benzonitrile oxide to provide a variety of sulfur heterocycles. Interestingly, the formation of