Kinetic solvent isotope effects (KSIE) were measured for the hydrolyses of acetals of benzaldehydes in aqueous solutions covering the pH (pD) range of 1-6. For p-methoxybenzaldehyde diethyl acetal, kD+/kH+ = 1.8-3.1, depending on the procedure used to calculate the KSIE and on the pH (pD) range used
Extreme solvent effects on reaction rate constants at supercritical fluid conditions
✍ Scribed by K. P. Johnston; Charles Haynes
- Publisher
- American Institute of Chemical Engineers
- Year
- 1987
- Tongue
- English
- Weight
- 984 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0001-1541
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