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External magnetic field dependent influence of lanthanide ions on the chemistry of radical pairs in micelles

✍ Scribed by Nicholas J. Turro; Xuegong Lei; Ian R. Gould; Matthew B. Zimmt

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 244 KB
Volume: 120
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)85627-x

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✦ Synopsis

The behavor of geminate inplet benzyl radical pairs in anionic micelles has been invectigated us a function of added lanthanide ions ( (\mathrm{Ln}^{3+}) ) in the presence and absence of a laboratory Tield Although the percent of glminate radical coupling is insensituve to the nature of added (\mathrm{Ln}^{3-}) in the absence of a laboratory field (exeept for 3 salt ellect) in the presence of a laboratory field the percent cage is significantly al[ected by paramagnetic (\mathrm{Ln}^{3+}) ions but not by diamagnetic (\mathrm{Ln}^{7+}) ions or by (\mathrm{Eu}^{3+})

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