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Extending the scope of enantiomer resolution by complexation gas chromatography

✍ Scribed by Schurig, Volker; Buerkle, Waldemar


Book ID
120192069
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
1000 KB
Volume
104
Category
Article
ISSN
0002-7863

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## High -resolution open-tubular columns coated with solutions of heptakis(2,3,6-tri-O-methyl)-P-cyclodextrin (Phase I) or heptakis(2,6-di-O-methyl-3-O-trifluoroacetyl)-~-cyclodextrin (Phase I/) in moderately polar polysiloxanes such as OV-1701 (5% cyanopropyl/7% pheny1/88% methylpolysiloxane) and

Enantiomer separation of 2-halocarboxyli
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The enantiomer separation of 2-halocarboxylic acid esters on two chiral nickel(l1) bis-((perfluoroacy1)terpeneketonates) by complexation gas chromatography is described. The quantitative enantiomer separation of branched 2-halocarboxylic acid esters is achieved with nickel ( 11) bis (3-(heptafluorob