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Exploratory studies probing the intermediacy of azomethine ylides in the photochemistry of N-phthaloyl derivatives of α-amino acids and β-amino alcohols

✍ Scribed by Ung Chan Yoon; Chan Woo Lee; Sun Wha Oh; Patrick S Mariano

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 632 KB
Volume: 55
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(99)00702-4

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✦ Synopsis

Ab~ract: Exploratory photochemical studies with N-phthaloyl derivatives of glutamic acid, aspartic acid, serine, threonine and analogous carboxylic acids and alcohols have been conducted to determine the generality of azomethine ylide forming decarboxylation and retro-aldol fragmentation reactions. Preferences in the competition between these excited state reaction pathways have been determined by studies with phthalimides which contain both a-amino acid and [3-aminoethanol groups.

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