The capillary electrophoretic separation of cationic enantiomers with single-isomer multivalent anionic resolving agents was reexamined with the help of the charged resolving agent migration model. Three general model parameters were identified that influence the shape of the separation selectivity
✦ LIBER ✦
Experimental verification of a predicted, previously unseen separation selectivity pattern in the capillary electrophoretic separation of noncharged enantiomers by octakis(2,3-diacetyl-6-sulfato)-γ-cyclodextrin
✍ Scribed by Wenhong Zhu; Wen-Shan Li; Frank M. Raushel; Gyula Vigh
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 211 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0173-0835
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The new, single-isomer, octakis 2,3-diacetyl-6-sulfato -␥-cyclodextrin Ž . ODAS-␥ CD has been used for the capillary electrophoretic separation of the enantiomers of weak acids, mostly nonsteroidal anti-inflammatory agents, in a high pH background electrolyte where all the acidic analytes were fully