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Experimental thermodynamics of the helix–random coil transition. II. Calorimetric measurement of transition enthalpies of poly A in acid aqueous solution

✍ Scribed by H. Klump; Th. Ackermann; E. Neumann


Publisher
Wiley (John Wiley & Sons)
Year
1969
Tongue
English
Weight
464 KB
Volume
7
Category
Article
ISSN
0006-3525

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## Abstract The thermal helix–coil transition of four samples of poly(γ‐benzyl‐L‐glutamate) in the dioxane–dichloroacetic acid (DCA) mixture was studied by optical rotatory dispersion method. The transition occurred at very high DCA content (97.5% by weight) in this system. The transition parameter