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Experimental test of karplus-type relationships for 3J(Sn, C) and 3J(Sn, H)

✍ Scribed by T. N. Mitchell; J. C. Podesta; A. Ayala; A. B. Chopa

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 323 KB
Volume: 26
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260260612

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✦ Synopsis

Multinuclear ('H, "C, lI9Sn) NMR data are presented for a series of compounds of the type XMe,SnCHRCHRCO,Me (X = Me, C1; R, R' = Me, Ph). Values of 'J(H, H), 'J(Sn, H) and 'J(S0, C) were used to assign the preferred conformations of these compounds and at the same time to test the empirical relationships proposed previously for 'J(Sn, C) and (indirectly) 'J(Sn, H); the validity of these relationsbips was confirmed.

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