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Experimental study of the rydberg orbitals of large molecules

โœ Scribed by M. B. Robin

Book ID
104578239
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
340 KB
Volume
6
Category
Article
ISSN
0020-7608

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๐Ÿ“œ SIMILAR VOLUMES

Experimental evidence to Rydbergization
Experimental evidence to Rydbergization of antibonding molecular orbitals
โœ M. Chergui; N. Schwentner ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 571 KB

Experimental evidence is presented for the process of molecular orbital Rydbergization postulated by Mulliken, whereby an antibonding orbital continuously changes its character from predominantly Rydberg to predominantly valence on its way to dissociation. By matrix-isolation spectroscopy of the A '

Comments on antiresonance lineshapes in
Comments on antiresonance lineshapes in the rydberg spectra of large molecules
โœ S.D. Druger ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 352 KB

The configuration interaction mechanism proposed by Florida, Schcps and Rice is shown inadequate to explain either the nonvanishing antiresonance minimum in the Rydberg absorption spectrum of naphthalene or the absence of obsesvabk antiresonances in general. The results of a treatment based on relax

A model for the quantum dynamics of Rydb
A model for the quantum dynamics of Rydberg states of large molecules
โœ Michael Thoss; Wolfgang Domcke ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 492 KB

A model for the dynamics of high Rydberg states in isolated large molecules is proposed. The model accounts for the interaction between the electron and the vibrational degrees of freedom of the core. These are modelled by an Ohmic bath in thermal equilibrium. A reduced-density-matrix description is