Experimental Study of NO Reaction with Isoprene Hydroxyalkyl Peroxy Radicals
β Scribed by Zhang, Dan; Zhang, Renyi; North, Simon W.
- Book ID
- 127354060
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 104 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The gas-phase reaction of NO 3 radicals with isoprene was investigated under flow conditions at 298 K in the pressure range 6.8 Ο½ P(mbar) Ο½ 100 using GC-MS/FID, direct MS, and long-path FT-IR spectroscopy as detection techniques. By means of a relative rate method, the rate constant for the primary
The multireference CI method using the active reaction subsystem was carried out to elucidate the electronic structures of both the ground and excited states of aminoperoxy radical (HzNOz) and its excitation energies. The system constructed of the four reaction natural orbitals and five electrons wa
## Abstract A direct kinetics study of the productβforming channels of the reaction of isopreneβderived hydroxyalkylperoxy radicals with NO has been performed at 100 Torr pressure and 298 K using the turbulent flow technique with highβpressure chemical ionization mass spectrometry for the detection
The yields of C, and C, alkyl nitrates from neopentane, 2-methylbutane, 2-methylpentane, 3-methylpentane, and cyclohexane have been measured in irradiated CH30NO-NO-alkane-air mixtures at 298 t-2 K and 735-torr total pressure. Additionally, OH radical rate constants for neopentyl nitrate, 3-nitro-2-