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Experimental and Theoretical Studies of Isoprene Reaction with NO 3

✍ Scribed by Suh, Inseon; Lei, Wenfang; Zhang, Renyi


Book ID
126910305
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
113 KB
Volume
105
Category
Article
ISSN
1089-5639

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The gas-phase reaction of NO 3 radicals with isoprene was investigated under flow conditions at 298 K in the pressure range 6.8 Ο½ P(mbar) Ο½ 100 using GC-MS/FID, direct MS, and long-path FT-IR spectroscopy as detection techniques. By means of a relative rate method, the rate constant for the primary

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## Abstract Rate coefficients for the gas‐phase reaction of isoprene with nitrate radicals and with nitrogen dioxide were determined. A Teflon collapsible chamber with solid phase micro extraction (SPME) for sampling and gas chromatography with flame ionization detection (GC/FID) and a glass reacto