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Experimental Studies and Theoretical Interpretation of the Calorimetric Effects Accompanying Ion Adsorption at Oxide/Electrolyte Interfaces: Application of Flow Adsorption Calorimetry †

✍ Scribed by Rudziński, Władysław; Charmas, Robert; Piasecki, Wojciech; Groszek, Alexander J.; Thomas, Fabien; Villieras, Frederic; Prelot, Benedict; Cases, Jean M.


Book ID
126094207
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
131 KB
Volume
15
Category
Article
ISSN
0743-7463

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Calorimetric Effects and Temperature Dep
✍ W. Rudzinski; W. Piasecki; G. Panas; R. Charmas 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 146 KB

The temperature dependence of surface charge isotherms in the system where PZC and CIP do not coincide was subjected to a quantitative theoretical-numerical analysis. That analysis, based on the TLM model of the oxide/electrolyte interface, and on the assumption of the 2-pK charging mechanism, would