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Calorimetric Effects and Temperature Dependence of Simple Ion Adsorption at Oxide−Electrolyte Interface: A Theoretical Analysis Based on the Triple-Layer Complexation Model

✍ Scribed by Rudzinski, W.; Charmas, R.; Cases, J. M.; Francois, M.; Villieras, F.; Michot, L. J.


Book ID
127296403
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
341 KB
Volume
13
Category
Article
ISSN
0743-7463

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The temperature dependence of surface charge isotherms in the system where PZC and CIP do not coincide was subjected to a quantitative theoretical-numerical analysis. That analysis, based on the TLM model of the oxide/electrolyte interface, and on the assumption of the 2-pK charging mechanism, would