1pK and 2pK Protonation Models in the Theoretical Description of Simple Ion Adsorption at the Oxide/Electrolyte Interface: The Analysis of Temperature Dependence of Potentiometric Titration Curves

Calorimetric Effects and Temperature Dep

Calorimetric Effects and Temperature Dependence of Simple Ion Adsorption at Oxide/Electrolyte Interfaces: The Systems in Which PZC and CIP Do Not Coincide

✍ W. Rudzinski; W. Piasecki; G. Panas; R. Charmas 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 146 KB

The temperature dependence of surface charge isotherms in the system where PZC and CIP do not coincide was subjected to a quantitative theoretical-numerical analysis. That analysis, based on the TLM model of the oxide/electrolyte interface, and on the assumption of the 2-pK charging mechanism, would