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Experimental Nonadditivity of Pressure Lineshifts in the System of Transitions of the Ammonia Molecule

✍ Scribed by A.F. Krupnov

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
87 KB
Volume
176
Category
Article
ISSN
0022-2852

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✦ Synopsis

Experimental evidence of inequality of algebraic sums of pressure lineshift parameters of transitions along different paths connecting the same initial and final energy levels in the spectrum of the ammonia molecule is demonstrated. Though such a possibility follows, e.g., from different values of parameters of nearest approach of perturbing molecules b 0 for different transitions in Anderson-type theories (and similar effects in other theories), up to now it lacked experimental evidence. Some consequences of the phenomenon and further studies are discussed.

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