Experimental evidence for the gaseous HSO3• radical. The key intermediate in the oxidation of SO2 in the atmosphere

✍ Scribed by Helge Egsgaard; Lars Carlsen; Helena Florencio; Thomas Drewello; Helmut Schwarz

• Book ID: 103026935
• Publisher: Elsevier Science
• Year: 1988
• Tongue: English
• Weight: 328 KB
• Volume: 148
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(88)80327-0

✦ Synopsis

The HSO; radical has been generated and characterized by neutralization/reionization mass spectmmetry. The HSO; radical exhibits a minimum lifetime of 0.7 ps when isolated in the gas phase. The principal unimolecular decomposition paths of HSO, were found to be loss of 'OH and 0, respectively.