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Computational Study of the Oxygen Initiated Decomposition of 2-Oxepinoxy Radical: A Key Intermediate in the Oxidation of Benzene

✍ Scribed by Merle, John K.; Hadad, Christopher M.

Book ID
126325759
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
470 KB
Volume
108
Category
Article
ISSN
1089-5639

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The HSO; radical has been generated and characterized by neutralization/reionization mass spectmmetry. The HSO; radical exhibits a minimum lifetime of 0.7 ps when isolated in the gas phase. The principal unimolecular decomposition paths of HSO, were found to be loss of 'OH and 0, respectively.