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Experimental Evidence for Linear Metal—Azido Coordination: The Binary Group 5 Azides [Nb(N3)5], [Ta(N3)5], [Nb(N3)6]-, and [Ta(N3)6]-, and 1:1 Acetonitrile Adducts [Nb(N3)5(CH3CN)] and [Ta(N3)5(CH3CN)].

✍ Scribed by Ralf Haiges; Jerry A. Boatz; Thorsten Schroer; Muhammed Yousufuddin; Karl O. Christe


Publisher
John Wiley and Sons
Year
2006
Weight
18 KB
Volume
37
Category
Article
ISSN
0931-7597

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Experimental Evidence for Linear Metal–A
✍ Ralf Haiges; Jerry A. Boatz; Thorsten Schroer; Muhammed Yousufuddin; Karl O. Chr 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB 👁 1 views

## Dedicated to Professor Reint Eujen on the occasion of his 60th birthday Whereas the existence of numerous binary transition-metalazido complexes has been reported, [1][2][3] no binary Group 5 azides are known. Only a limited number of partially azidosubstituted compounds of vanadium, niobium, an