ChemInform Abstract: Preparation and Characterization of the Binary Group 13 Azides M(N3)3 and M(N3)3·CH3CN (M: Ga, In, Tl), [Ga(N3)5]2-, and [M(N3)6]3- (M: In, Tl).
✍ Scribed by Ralf Haiges; Jerry A. Boatz; Jodi M. Williams; Karl O. Christe
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 27 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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Complexes of the type [M{N(O)C(CN) 2 }(PPh 3 ) n ] (M = Cu I , oxygen atom (silver). In addition the two copper and silver complexes [M{N(O)C(CN) 2 }(PPh 3 ) 2 ] 2 are not isostructural but Ag I , n = 2, 3) were synthesized by metathesis of K[N(O)C(CN) 2 ] and [M(NO 3 )(PPh 3 ) n ]. The complexes we