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Experimental and theoretical study of the recombination reaction of FC(O)O radicals

✍ Scribed by A.E. Croce; C.J. Cobos; E. Castellano


Book ID
103667335
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
928 KB
Volume
211
Category
Article
ISSN
0301-0104

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πŸ“œ SIMILAR VOLUMES


FTIR product study of the self-reaction
✍ Timothy J. Wallington; Michael D. Hurley; M. Matti Maricq πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 581 KB

Fourier transform infrared spectroscopy has been used to identify and quantify FC(O)OOC (0)F and COP as products following the self-reaction of FC(O)Os radicals. Fmm the observed product yields, it was determined that the reaction proceeds pro dominately (80%+20%), if not exclusively, via FC(O)O,+FC

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A pulse radiolysis system was used to study the kinetics of the reaction of FC(0)Oz radicals with NOz. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be (5.5 ? 0.6) X 10-l' cm3 molecule-' 5-l a t 296 K and 500-1000 mbar pressure

Theoretical study of the O + HSO reactio
✍ M. Y. Ballester; A. J. C. Varandas πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 199 KB

## Abstract A quasi‐classical trajectory study of the title reaction is reported using a global, double, many‐body expansion potential energy surface for HSO~2~. Calculations are presented for specific translational energies and rovibrational states of the reactants, showing that formations of H +