Fourier transform infrared spectroscopy has been used to identify and quantify FC(O)OOC (0)F and COP as products following the self-reaction of FC(O)Os radicals. Fmm the observed product yields, it was determined that the reaction proceeds pro dominately (80%+20%), if not exclusively, via FC(O)O,+FC
Experimental and theoretical study of the recombination reaction of FC(O)O radicals
β Scribed by A.E. Croce; C.J. Cobos; E. Castellano
- Book ID
- 103667335
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 928 KB
- Volume
- 211
- Category
- Article
- ISSN
- 0301-0104
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π SIMILAR VOLUMES
A pulse radiolysis system was used to study the kinetics of the reaction of FC(0)Oz radicals with NOz. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be (5.5 ? 0.6) X 10-l' cm3 molecule-' 5-l a t 296 K and 500-1000 mbar pressure
## Abstract A quasiβclassical trajectory study of the title reaction is reported using a global, double, manyβbody expansion potential energy surface for HSO~2~. Calculations are presented for specific translational energies and rovibrational states of the reactants, showing that formations of H +