Experimental and theoretical study of carbon suboxide C3O2, protonated carbon suboxide C3HO2+ and C3HO2· radical in the gas phase
✍ Scribed by J. Tortajada; G. Provot; J.-P. Morizur; J.-F. Gal; P.-C. Maria; R. Flammang; Y. Govaert
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 939 KB
- Volume
- 141
- Category
- Article
- ISSN
- 0168-1176
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The photolysis of carbon suboxide (C,O,) at 248 and 308 nm was investigated by monitoring laser-induced fluorescence (LIF) of the product C&0(X3x -). At 308 nm the C&O(X31; -) appears immediately after the photolysis flash followed by a slow decay. This clean source of C&O(X'Z -> was used to measure
## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0