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Experimental and theoretical study of carbon suboxide C3O2, protonated carbon suboxide C3HO2+ and C3HO2· radical in the gas phase

✍ Scribed by J. Tortajada; G. Provot; J.-P. Morizur; J.-F. Gal; P.-C. Maria; R. Flammang; Y. Govaert


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
939 KB
Volume
141
Category
Article
ISSN
0168-1176

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## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0