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Experimental and Theoretical Studies of the Potential Interconversion of the Amine–Borane iPr2NH·BH(C6F5)2 and the Aminoborane iPr2N=B(C6F5)2 Involving Hydrogen Loss and Uptake

✍ Scribed by Alasdair P. M. Robertson; George R. Whittell; Anne Staubitz; Kajin Lee; Alan J. Lough; Ian Manners


Book ID
102166667
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
404 KB
Volume
2011
Category
Article
ISSN
1434-1948

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✍ Yann Sarazin; Simon J. Coles; David L. Hughes; Michael B. Hursthouse; Manfred Bo 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 227 KB 👁 1 views

## Abstract Ph~3~SnN(SiMe~3~)~2~ (1) was prepared in good yields by reaction of [{NaN(SiMe~3~)~2~}~2~·THF] (2) with Ph~3~SnF. Treatment of 1 with [H(OEt~2~)~2~][H~2~N{B(C~6~F~5~)~3~}~2~] (4) in dichloromethane afforded the stannylium cation [Ph~3~Sn(OEt~2~)][H~2~N{B(C~6~F~5~)~3~}~2~] (5), which was