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Experimental and Computational Study of the Conrotatory Ring Opening of Various 3-Chloro-2-azetines

✍ Scribed by Mangelinckx, Sven; Speybroeck, Veronique Van; Vansteenkiste, Peter; Waroquier, Michel; Kimpe, Norbert De


Book ID
120211613
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
588 KB
Volume
73
Category
Article
ISSN
0022-3263

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Labelling studies of the ring opening of
✍ Mark S. Baird πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 210 KB

upon Tyne , Newcastle upon Vne , NE1 7RU. 1-Bromo-2-chloro-3,3-dimethylcyclopropene reacts with methyl lithium in the presence of 2,3\_dimethylbut-2-ene at above -7OOC to give (4); 12 C labelling shows that C-2 of the cyclopropane becomes the centre carbon of the allene.