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Experimental and Computational Studies of the Phenyl Radical Reaction with Allene †

✍ Scribed by Park, J.; Tokmakov, I. V.; Lin, M. C.

Book ID
125893105
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
273 KB
Volume
111
Category
Article
ISSN
1089-5639

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✍ H. J. van der Ploeg; J. Knotnerus; A. F. Bickel 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 479 KB

## Abstract The free‐radical addition of 1‐propanethiol, benzenethiol (thiophenol) and α‐toluenethiol (benzyl mercaptan) to allene in benzene solution has been investigated. At high allene/thiol ratios the two sulfides resulting from the addition of one mole of RSH to allene (isopropenyl‐SR and al