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Strained Allenes as Dienophiles in the Diels−Alder Reaction: An Experimental and Computational Study

✍ Scribed by Nendel, Maja; Tolbert, Laren M.; Herring, Laura E.; Islam, Md. Nurul; Houk, K. N.


Book ID
127046205
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
148 KB
Volume
64
Category
Article
ISSN
0022-3263

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endo-exo Selectivity in Diels-Alder cycloadditions of several o-quinodimethanes (1-4) with acrylonitrile, 2-(5H)-furanone and N-methylmaleimide has been investigated in acetonitrile solution. Transition structures of the cycloaddition of the parent o-QDM (1), (E,E)-1,8-dimethyl-o-QDM (2), isoindene