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Expeditious Preparation of Various Δ9-6a,10a cis and trans 2-Substituted Tetrahydrocannabinoids.

✍ Scribed by Jean-Yves Goujon; Francoise Zammattio; Bernard Kirschleger

Publisher
John Wiley and Sons
Year
2003
Weight
94 KB
Volume
34
Category
Article
ISSN
0931-7597

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The Relative Stabilities of Substituted
The Relative Stabilities of Substituted cis- and trans-1,2,3,4,4a,9,10,10a-Octahydrophenanthrenes, Including Configurational Corrections in the Elad-Ginsburg Morphine Synthesis
✍ Rudolf O. Duthaler; David Ginsburg 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 German ⚖ 481 KB

The relative configuration of the title compounds has been determined by 'H-NMR measurements at 300 MHz. In contradistinction to prevailing opinion, it was found that 4-OXO derivatives prefer the cis-configuration. While the cis/truns ratio is 82: 18 for the parent 1,2,3,4,4a,9,10, lOa-octahydrophen