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Expedient synthesis of corroles by oxidant-mediated, direct α-α′ coupling of tetrapyrromethanes

✍ Scribed by Jae-Won Ka; Won-Seob Cho; Chang-Hee Lee

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
85 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Oxidant mediated coupling of tetrapyrromethanes resulted in the exclusive formation of meso-substituted corroles in more than 60% yields. The similar coupling reaction of 1,14-unsubstituted 16-oxatripyrromethane with 5-tolyldipyrromethane carried out in acetonitrile also gave expanded corroles as a single product. In both cases acid catalysts are not necessary for the direct a-a% coupling reaction.

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ChemInform Abstract: Expedient Synthesis of Corroles by Oxidant-Mediated, Direct .alpha±alpha.′ Coupling of Tetrapyrromethanes.
✍ Jae-Won Ka; Won-Seob Cho; Chang-Hee Lee 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

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