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Expanding the Application Range of Aldolases: Novel Asymmetric Syntheses of α-Methylated β-Hydroxy α-Amino Acids and β-Amino Alcohols

✍ Scribed by Katrin Baer; Nina Dückers; Werner Hummel; Harald Gröger

Book ID
112018789
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
223 KB
Volume
2
Category
Article
ISSN
1867-3880

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Concise enantio- and diastereoselective
Concise enantio- and diastereoselective synthesis of α-hydroxy-α-methyl-β-amino acids
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Reported here is an efficient procedure for enantio-and diastereoselective synthesis of pure b-amino acids that display a tert-hydroxyl functionality in the a-position. Key steps include a catalytic asymmetric aldol reaction and a modified Curtius rearrangement to form oxazolidinone intermediates, w