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Expanded Scope of the Asymmetric Hydrogenation of Minimally Functionalized Olefins Catalyzed by Iridium Complexes with Phosphite-Thiazoline Ligands

✍ Scribed by Mazuela, Javier; Pàmies, Oscar; Diéguez, Montserrat


Book ID
124078094
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
339 KB
Volume
5
Category
Article
ISSN
1867-3880

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Asymmetric hydrogenation of aromatic ole
✍ Guopin Xu; Scott R. Gilbertson 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 196 KB

The synthesis of a series of phosphine-oxazoline ligands is reported. This ligands are synthesized by reaction of a phosphine chloride with the secondary nitrogen of proline. Upon coordination to iridium the resulting complexes can be used in the asymmetric hydrogenation of simple olefins. The effec