Exo- und endo-Bicyclo[3,2,2]nonanol-(6)
✍ Scribed by Gerhard Mann; Jürgen Braband; Manfred Mühlstädt
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 284 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0044-2402
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📜 SIMILAR VOLUMES
## Abstract The synthesis of the title compounds and their hydrolysis products in 70% dioxane are described.
Wle friiher berlchtet 1,2) nlmmt die Solvolysegeschwlndlgkelt von exo-Blcyclo-(n, l,O)-alkyltosylaten (I) In der Folge n = 5.4.3 ab, wobel der Effekt helm Ubergang von n = 4 nach n = 3 besonders ausgeprlgt 1st (vgl. Tab. 1). Dies 1st ver-st&ndllch, well die mit der Ionlsatlon verbundene Dlsrotatlon
**Synthesis of __endo__‐ and __exo__‐1,3‐dimethyl‐2,9‐dioxabicyclo[3.3.1]nonane** The synthesis of a host‐specific substance in norway spruce infested by __Trypodendron lineatum__ OLIV. is described (__cf. scheme 1 and 2__). Alkylation of the acetyl‐acetone di‐anion (II) with 3‐methyl‐3‐buten‐1‐yl‐